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According to Intel's 8080-8085 Assembly Language Programming guide, the OP Code 20 corresponds to the Read Interrupt Mask (RIM) instruction, and 30 corresponds to the Set Interrupt Mask (SIM) instruction.
But these interrupts were only available on the 8085. What did these instructions do on the earlier 8080 chipset? How do they work on the 8085?
The 8085 added two new instruction functions: SIM and RIM.
These instructions differ from the 8080 instructions in that each has multiple functions. The SIM instruction sets the interrupt mask and optionally writes one bit of data to the serial interface. The RIM instruction reads one bit from the serial interface (if one is present) and the interrupt mask into register A, the accumulator.
There are also differences with regard to signal processing signal processing. The new RST5.5, RST6.5, and RST7.5 hardware interrupts take priority over the Interrupt line at pin 14, the only interrupt on the 8080.
These instructions are NOPs on the 8080.
To answer your specific question, the 0x20 and 0x30 opcodes on the 8080 were undefined. In practice they were equivalent to NOP (0x00).
A handy table of 8080 instructions can be found here: http://pastraiser.com/cpu/i8080/i8080_opcodes.html
